KnE Materials Science

ISSN: 2519-1438

The latest conference proceedings on physical materials, energy materials, electrical materials.

Bismuth Molybdate-based Oxygen Ion Conductors: Synthesis and Properties

Published date: Oct 14 2018

Journal Title: KnE Materials Science

Issue title: Sino-Russian ASRTU Conference Alternative Energy: Materials, Technologies, and Devices

Pages: 14–23

DOI: 10.18502/kms.v4i2.3032

Authors:

Z A Mikhaylovskaya - zozoikina@mail.ru

E S Buyanova

S A Petrova

Abstract:

The present research is devoted to the synthesis and investigation of properties and structure of Ba-, Mn-, S-, and P- substituted Bi26Mo10O69. The complex oxides have been synthesized using conventional method. The samples were examined using XRPD, IR FT spectroscopy, Rietveld full profile structure refinement, SEM, laser diffraction, and densitometry. Photocatalytic properties were investigated at RhB oxidation under UV irradiation. Electrical conductivity was studied with impedance spectroscopy. As a result, the best samples of Ba-, Mn-, S-, and P- substituted Bi26Mo10O69 can be recommended as high ionic conductive materials.

Keywords: oxygen ion conductors, bismuth molybdate

References:

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[2] Zhao, X., Xu, T., Yao, W., et al. (2009). Synthesis and photoelectrochemical properties of thin bismuth molybdate film with various crystal phases. Thin Solid Films, vol. 517, pp. 5813–5818.


[3] Boivin, J-C. (2001). Structural and electrochemical features of fast oxide ion conductors. International Journal of Inorganic Materials, vol. 3, pp. 1261–1266.


[4] Sharma, N., Macquart, R. B., Christensen, M., et al. (2009). Structure and crystal chemistry of fluorite-related Bi38Mo7O78 from single crystal X-ray diffraction and ab initio calculations. Journal of Solid State Chemistry, vol. 182, pp. 1312–1318.


[5] Vannier, R. N., Mairesse, G., Abraham, F., et al. (1996). Bi26Mo10O

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