Published date: Mar 27 2024

Journal Title: KnE Life Sciences

Issue title: International Conference On Mathematics And Science Education (ICMScE 2022): Life Sciences

Pages: 29–39

DOI: 10.18502/kls.v8i1.15390

Gizella Mentari PutriPhysics Study Program, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi No. 229 Bandung, Indonesia

Endi Suhendendis@upi.eduPhysics Study Program, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi No. 229 Bandung, Indonesia

Muhamad Taufik UlhakimDepartment of Mechanical Engineering, Faculty of Engineering, Universitas Buana Perjuangan Karawang, Jl. HS. Ronggo Waluyo, Karawang, Indonesia

Andhy SetiawanPhysics Study Program, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudi No. 229 Bandung, Indonesia

Dani Gustaman SyarifCenter of Science and Technology of Applied Nuclear, National Nuclear Energy Agency of Indonesia (BATAN), Jl. Tamansari No. 71 Bandung, Indonesia

Herein, electrical properties of ethanol gas sensing based on Gd- and Mn- doped Fe2O3-LaFeO3-La2O3 thick films were investigated. The Gd- and Mn-doped Fe2O3- LaFeO3-La2O3 were synthesized by coprecipitation method and formed to thick films using screen-printing techniques with sintering temperature at 900 ∘C. X-ray diffraction and scanning electron microscopy were conducted to determine the crystal and morphological structures. The results showed that the synthesized materials have three phases i.e., tetragonal, cubic, and hexagonal, respectively for Fe2O3-LaFeO3-La2O3. Also, the average particle size is of about 0.51 μm. Among all those circumstances, synthesized materials indicate good performances as ethanol gas sensing that showed in the electrical properties’ measurement. It tested A differently in ethanol containing i.e., 0 ppm, 100 ppm, 200 ppm, and 300 ppm. The highest response to ethanol gases reached at 300 ppm, it is 332 with optimum temperature at 289∘C. We hope our findings could be beneficial and helpful in the perfect fabrication of ethanol gas sensors in future.

Keywords: electrical properties, thick films, doped, ethanol, sensors

[1] Umar A, Ibrahim AA, Nakate UT, Albargi H, Alsaiari MA, Ahmed F, et al. Fabrication and characterization of CuO nanoplates based sensor device for ethanol gas sensing application. Chem Phys Lett. 2021;763:138204.

[2] Zhang K, Qin S, Tang P, Feng Y, Li D. Ultra-sensitive ethanol gas sensors based on nanosheet-assembled hierarchical ZnO-In2O3 heterostructures. J Hazard Mater. 2020 Jun;391:122191.

[3] Wang C, Wang ZG, Xi R, Zhang L, Zhang SH, Wang LJ, et al. In situ synthesis of flower-like ZnO on GaN using electrodeposition and its application as ethanol gas sensor at room temperature. Sens Actuators B Chem. 2019;292:270–6.

[4] Gong Y, Wang Y, Sun G, Jia T, Jia L, Zhang F, et al. Carbon nitride decorated ballflower like Co3O4 hybrid composite: hydrothermal synthesis and ethanol gas sensing application. Nanomaterials (Basel). 2018 Feb;8(3):132.

[5] Elger AK, Hess C. Elucidating the mechanism of working SnO2 gas sensors using combined operando UV/Vis, Raman, and IR spectroscopy. Angew Chem Int Ed Engl. 2019 Oct;58(42):15057–61.

[6] Zhu L, Zeng W, Li Y, Yang J. Enhanced ethanol gas-sensing property based on hollow MoO3 microcages. Physica E. 2019;106:170–5.

[7] Hao P, Qiu G, Song P, Yang Z, Wang Q. Construction of porous LaFeO3 microspheres decorated with NiO nanosheets for high response ethanol gas sensors. Appl Surf Sci. 2020;515:146025.

[8] Xiang J, Chen X, Zhang X, Gong L, Zhang Y, Zhang K. Preparation and characterization of Ba-doped LaFeO3 nanofibers by electrospinning and their ethanol sensing properties. Mater Chem Phys. 2018;213:122–9.

[9] Theingi M, Tun KT, Aung NN. Preparation, characterization and optical property of LaFeO3 nanoparticles via sol-gel combustion method. SciMedicine Journal. 2019;1(3):151–7.

[10] Zhang T, Guo Y, Li C, Li Y, Li J, Zhao F, et al. The effect of LaFeO3@ MnO2 on the thermal behavior of energetic compounds: an efficient catalyst with core-shell structure. Adv Powder Technol. 2020;31(11):4510–6.

[11] Salah LM, Haroun M, Rashad MM. Structural, magnetic, and electrical properties of Gd-substituted LaFeO 3 prepared by co-precipitation method. Journal of the Australian Ceramic Society. 2018;54(2):357–68.

[12] Peng Y, Xia C, Cui M, Yao Z, Yi X. Effect of reaction condition on microstructure and properties of (NiCuZn)Fe2O4 nanoparticles synthesized via co-precipitation with ultrasonic irradiation. Ultrason Sonochem. 2021 Mar;71:105369.

[13] Zhang D, Yang Z, Yu S, Mi Q, Pan Q. Diversiform metal oxide-based hybrid nanostructures for gas sensing with versatile prospects. Coord Chem Rev. 2020;413:213272.

[14] Suhendi E, Ulhakim MT, Setiawan A, Syarif DG. The effect of SrO doping on LaFeO3 using yarosite extraction based ethanol gas sensors performance fabricated by coprecipitation method. International Journal of Nanoelectronics and Materials. 2019;12(2):185–92.

[15] Çolak H, Karaköse E. Gadolinium (III)-doped ZnO nanorods and gas sensing properties. Mater Sci Semicond Process. 2022;139:106329.

[16] E. Suhendi, M.T.U. Latifah, A. Setiawan, and D.G. Syarif, “Studies on the effect of MnO doping on LaFeO3 Ceramics in Comparison to Yarosite Mineral Properties for Ethanol Gas Sensors Performance.,” International Journal of Nanoelectronics & Materials. vol. 14, no. 4, p. 2021.

[17] Powar RR, Parale VG, Phadtare VD, Wategaonkar SB, Mane RK, Gunjkar JL, et al. Nanocrystalline spinel zinc-substituted cobalt ferrite thick film an efficient ethanol sensor. Mater Today Chem. 2021;22:100607.

[18] Suhendi E, Amanda ZL, Ulhakim MT, Setiawan A, And DG. Syarif, “The enhancement of ethanol gas sensors response based on calcium and zinc co-doped LaFeO3/Fe2O3 thick film ceramics utilizing yarosite minerals extraction as Fe2O3 precursor.,” Journal of Metals. Materials and Minerals. 2021;31(2):71–7.

[19] Saadat Niavol S, Milani Moghaddam H. SnO 2 nanoparticles/reduced graphene oxide nanocomposite for fast ethanol vapor sensing at a low operating temperature with an excellent long-term stability. J Mater Sci Mater Electron. 2021;32(5):6550–69.

[20] Raji P, Kumar KB. Investigation of Ti doping on the structural, optical, and magnetic properties of ZnO nanoparticles. J Mater Sci Mater Electron. 2021;32(9):11751–62.

[21] Ghobadifard M, Farhadi S, Mohebbi S. Catalytic performance of ZnFe 2 O 4 nanoparticles prepared from the [ZnFe 2 O (CH 3 COO) 6 (H 2 O) 3]· 2H 2 O complex under microwave irradiation. Res Chem Intermed. 2019;45(2):379–400.

[22] Yadav N, Singh A, Kaushik M. Hydrothermal synthesis and characterization of magnetic Fe3O4 and APTS coated Fe3O4 nanoparticles: physicochemical investigations of interaction with DNA. J Mater Sci Mater Med. 2020 Jul;31(8):68.

[23] Suhendi E, Putri AE, Ulhakim MT, Setiawan A, Syarif DG. “Investigation of ZnO doping on LaFeO3 / Fe2O3 prepared from yarosite mineral extraction for ethanol gas sensor applications.,” AIMS Materials Science. vol. 9, no. 1, p. 2022.

[24] Wang Z, Li F, Wang H, Wang A, Wu S. An enhanced ultra-fast responding ethanol gas sensor based on Ag functionalized CuO nanoribbons at room-temperature. J Mater Sci Mater Electron. 2018;29(19):16654–9.

[25] Mahmood MH, Maleque MA. Effective parameter of Nano-CuO coating on CO gassensing performance and heat transfer efficiency. Arab J Sci Eng. 2021;46(7):6557– 66.

[26] Mehmood S, Zhao X, Bhopal MF, et al. MoO2-Ni-graphene ternary nanocomposite for a high-performance room-temperature ethanol gas sensor. Appl Surf Sci. 2021;554:149595.

[27] Li P, Cao C, Shen Q, Bai B, Jin H, Yu J, et al. Cr-doped NiO nanoparticles as selective and stable gas sensor for ppb-level detection of benzyl mercaptan. Sens Actuators B Chem. 2021;339:129886.

[28] Zhou Q, Chen W, Xu L, Kumar R, Gui Y, Zhao Z, et al. Highly sensitive carbon monoxide (CO) gas sensors based on Ni and Zn doped SnO2 nanomaterials. Ceram Int. 2018;44(4):4392–9.

[29] Ariyani NI, Syarif DG, Suhendi E. “Fabrication and Characterization of Thick Film Ceramics La0, 9Ca0, 1FeO3 for Ethanol Gas Sensor using Extraction of Fe2O3 from Yarosite Mineral.,” In: IOP Conference Series: Materials Science and Engineering. pp. 12037. IOP Publishing (2018).

[30] Liu C, Navale ST, Yang ZB, Galluzzi M, Patil VB, Cao PJ, et al. Ethanol gas sensing properties of hydrothermally grown a-MnO2 nanorods. J Alloys Compd. 2017;727:362–9.

[31] Srinivasan P, Ezhilan M, Kulandaisamy AJ, Babu KJ, Rayappan JB. Room temperature chemiresistive gas sensors: challenges and strategies—a mini review. J Mater Sci Mater Electron. 2019;30(17):15825–47.

[32] Hu X, Zhu Z, Chen C, Wen T, Zhao X, Xie L. Highly sensitive H2S gas sensors based on Pd-doped CuO nanoflowers with low operating temperature. Sens Actuators B Chem. 2017;253:809–17.

[33] A. Mirzaei, J.-H. Lee, S.M. Majhi, et al., “Resistive gas sensors based on metal-oxide nanowires.” Journal of Applied Physics. vol. 126, no. 24, p. 2019. https://doi.org/10.1063/1.5118805.